|
|
p-coumaric_acid + CoA + ATP <=> 4-coumaroyl-CoA + AMP + diphosphate
|
6.2.1.12
4-coumarate---CoA ligase
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.30
phenylacetate---CoA ligase
|
–
–
–
|
| |
BRENDA:
BR63
KEGG:
R01616
MetaCyc:
4-COUMARATE--COA-LIGASE-RXN
SABIO-RK:
1761
|
|
|
|
(4-coumaroyl)acetyl-CoA + H2O <=> 4-coumaroyl-diketide + CoA + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11254
|
|
|
|
feruloyl_diketide + 4-coumaroyl-CoA + H+ <=> demethoxycurcumin + CoA + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21156
|
|
|
|
4-coumaroyl-diketide + 4-coumaroyl-CoA + H+ <=> bisdemethoxycurcumin + CoA + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21157
|
|
|
|
H+ + 4-coumaroyl-CoA + malonyl-CoA <=> (4-coumaroyl)acetyl-CoA + CoA + CO2
|
2.3.1.218
phenylpropanoylacetyl-CoA synthase
|
–
|
| |
BRENDA:
BR50411
KEGG:
R08805
MetaCyc:
RXN-11220
|
|
|
|
4-coumaroyl-diketide + feruloyl-CoA + H+ <=> demethoxycurcumin + CoA + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21158
|
|
|
|
feruloyl_diketide + feruloyl-CoA + H+ <=> curcumin + CoA + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21155
|
|
|
|
feruloylacetyl-CoA + H2O <=> feruloyl_diketide + CoA + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21154
|
|
|
|
H+ + feruloyl-CoA + malonyl-CoA <=> feruloylacetyl-CoA + CoA + CO2
|
2.3.1.218
phenylpropanoylacetyl-CoA synthase
|
–
|
| |
BRENDA:
BR50410
KEGG:
R08806
MetaCyc:
RXN-11221
|
|
|
|
S-adenosyl-L-methionine + caffeoyl-CoA <=> H+ + feruloyl-CoA + S-adenosyl-L-homocysteine
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
|
–
|
| |
BRENDA:
BR43863
KEGG:
R01942
MetaCyc:
CAFFEOYL-COA-O-METHYLTRANSFERASE-RXN
|
|
